New Optical Tools for Spectral Diagnostics of Liquid Solutions

Optical tools were used for the diagnostics of the water quality for different reservoirs in many countries [1-6]. These tools are based on the devices of spectrophotometry and spectroellipsometry [7-9]. Spectrophotometric devices deliver one spectrum that reflects of spectral optical properties for liquid solution a knowledge of which allows the accurate interpretation of measured reflection and attenuation spectra in terms of chemicals concentrations. Spectroellipsometric devices deliver two spectrums that show polarized optical properties of liquid solutions basing on the registration of optical polarization effects appearing under reflection or deformation of the light wave as a result of its interaction with studied object. In the solid physics, Spectrophotometry and Spectroellipsometry gives possibility to measure simultaneously amplitude and phase characteristics of studied object and allows the precise definition of the film thickness and optical constants for film material. The diagnostics of liquids gives possibility to assess the concentration of chemicals dissolved and weighed in the liquid, as well as to determine the spots of pollutants on the liquid surface. Kovalev et al. [7,8] developed the spectroellipsometry with binary modulation of polarization state. It is based on the elements of polarization optics and allows the measurement within wide spectrum. Optical devices proposed by Kovalev et al. [7,8] have not moving polarization elements. They were used in framework of hydrochemical investigations in South Vietnam for the diagnostics of different water objects including rivers, basins for fish industry and aquatories of South-China Sea [2,9]. These investigations have shown astonishing responsiveness and reliability of measurement data a mathematical analysis of which allows the assessment of water chemical characteristics. Really it is needed to solve multi-channel inverse task when spectrophotometric and spectroellipsometric data are interpreted as the concentrations of chemical substances in the solution sample [6-9]. Certainly, optical measurements are characterized by stability of spectral images.


Introduction
Optical tools were used for the diagnostics of the water quality for different reservoirs in many countries [1][2][3][4][5][6]. These tools are based on the devices of spectrophotometry and spectroellipsometry [7][8][9]. Spectrophotometric devices deliver one spectrum that reflects of spectral optical properties for liquid solution a knowledge of which allows the accurate interpretation of measured reflection and attenuation spectra in terms of chemicals concentrations. Spectroellipsometric devices deliver two spectrums that show polarized optical properties of liquid solutions basing on the registration of optical polarization effects appearing under reflection or deformation of the light wave as a result of its interaction with studied object. In the solid physics, Spectrophotometry and Spectroellipsometry gives possibility to measure simultaneously amplitude and phase characteristics of studied object and allows the precise definition of the film thickness and optical constants for film material. The diagnostics of liquids gives possibility to assess the concentration of chemicals dissolved and weighed in the liquid, as well as to determine the spots of pollutants on the liquid surface. Kovalev et al. [7,8] developed the spectroellipsometry with binary modulation of polarization state.
It is based on the elements of polarization optics and allows the measurement within wide spectrum. Optical devices proposed by Kovalev et al. [7,8] have not moving polarization elements. They were used in framework of hydrochemical investigations in South Vietnam for the diagnostics of different water objects including rivers, basins for fish industry and aquatories of South-China Sea [2,9]. These investigations have shown astonishing responsiveness and reliability of measurement data a mathematical analysis of which allows the assessment of water chemical characteristics.
Really it is needed to solve multi-channel inverse task when spectrophotometric and spectroellipsometric data are interpreted as the concentrations of chemical substances in the solution sample [6][7][8][9]. Certainly, optical measurements are characterized by stability of spectral images.

Method
Photometers and refractometers are widely used to study the optical properties of liquids in various fields of science and technology. As a rule, the accuracy of determining the refractive index and absorption coefficient is significantly related to the Abstract Three new optical devices has been design and constructed for the operative diagnostics of medical, biological and water solutions using state-of-the-art technology of optical inverse tasks solution in wavelength range from 350nm to 780nm. The structures of optical devices have the elements for the assessment of optical properties of liqueds and software for the concentration evaluation of chemicals in the solutions. One of the functions optical devices is recognition of solutions to define their classes using a database of spectral standards. The using optical devices in the expedition conditions in the hard-to-reach regions when there no exists chemical laboratory for operative analysis can be unique possibility to know a solution quality. One of such situations is mission to Mars. This paper represents results of optical diagnostics of the water objects in South Vietnam and Siberia when the water quality of these objects is assessed and their optical spectral images are formed. Measurement procedure is described to be as the instruction for each of three optical devices operation.  [5,6] for solutions with small concentration a linear function f provides precision of optical inverse task solution no less 99.8±0.2 percents.

Keywords:
A using the ASEDMS as measuring device allows the simultaneously two spectra that reflect the ellipsometric angles ∆ (0°-360°) and Ψ (0°-90°) where ∆ is the phase difference before and after the reflection (phase shift); angle Ψ corresponds to the amplitude ratio during reflection. The functional representation of cos∆ and tanΨ is defined by the ratio of complex Fresnel coefficients [10].
The ASEDMS delivers two spectra SΨ(λ) and S∆(λ) an analysis of which allows the assessment of physical and chemical properties of studied liquid solution. Precision of these assessments depend on the using software [6].       [12,13].  Coefficients {a ij } are assessed during the ASRDMS training, when fully known liquid solution sample are studied. Really a decision concerning liquid solution quality can be made only on the base of its standard spectral image that was earlier prepared [12,13].

Copy@ Ferdenant A Mkrtchyan
Example of such spectral digital standard is given in Table 1 Figure   4 represents spectral images of different water objects located in South Vietnam. Figure 6 shows spectral images of different water bodies of northern latitudes. Figure 7 characterizes the spectral changes of Kara Sea depending on the season. Table 2 shows some results of inverse task solution using software.

Conclusion
Three optical devices considered in this paper deal with operative diagnostics of the water reservoirs, chemical and biological solutions giving their hydrochemical state and providing the detection of extremely developing situations. These devices provide the collection and analysis of the data from multiple sources including in-situ measurements of the hydrochemical characteristics using optical tools [14]. The AUSDMS can realize measurements in the real time of moving regime when part of sky-light adapter is located below the liquid level.

Conflicts of Interest
The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analyses or interpretation of data; in the writing of the manuscript, or in the decision to publish the results.